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Serum levels of vitamin B12. People with vitamin B12 cobalamin deficiency may be prescribed a high dosage as treatment though this may yield headaches as a side effect. Vitamin B Complex Benefits Infographic Vitamin B Complex Benefits Vitamin B Vitamin B Complex Research has yet to show how or why vitamin B-2 also known as riboflavin helps prevent migraines. Vitamin b headache . One common symptom of B12 deficiency is headaches. The serum vitamin B 12 levels in the headache and control groups were 27301 7677 and 31622 7453 pgml with the difference determined as statistically significant p 0003. The phase IV clinical study analyzes which people take Vitamin b12 and have Headache. Vitamin B-2 is a water-soluble vitamin that plays a role in several physiological processes including skin function. It can also be used as supplements. If taken in mega doses as some do it can cause headache especially the Niacin b3 which can be associated with altered pain sensation. And...